Studies show that the sets of hazardous materials transportation road can be found quickly through the proposed road screening algorithm based on GA-LM-NN, whereas the distribution route Pareto solutions with different levels of robustness can be found rapidly through the proposed multi-objective robust optimization model and algorithm. The algorithm uses an improved strategy to complete the selection operation, applies partial matching cross shift and single ortho swap methods to complete the crossover and mutation operation, and employs an exclusive method to construct Pareto optimal solutions. A multi-objective genetic algorithm is designed to solve the problem according to the characteristics of the model. A multi-objective robust optimization model with adjustable robustness is constructed for the hazardous materials transportation problem of single distribution center to minimize transportation risk and time. For road screening issues of hazardous materials transportation, a road screening algorithm of hazardous materials transportation is built based on genetic algorithm and Levenberg–Marquardt neural network (GA-LM-NN) by analyzing 15 attributes data of each road network section. The optimization scheme may be a security risk if road screening is not completed before the distribution route is optimized. Route optimization of hazardous materials transportation is one of the basic steps in ensuring the safety of hazardous materials transportation.
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